Here are some pictures of the "splotches" (click the image to advance through the pictures). They can range from small specks of paint to splotches that are a couple inches wide or more. I'm still troubleshooting, but any advice or suggestions would be greatly appreciated! Below are some of the areas I'm troubleshooting if it helps:
- Paper: Using Rives BFK, which is often recommended among gum bichromate printers. I can test another paper, but I sure like this stuff. It dries flat, hold up great to multiple washes, doesn't stain, shows good detail... I'm currently working on large 40"x50" prints, so I need a paper that is available in a large roll. I sincerely hope the Rives paper isn't the problem.
- Paints: It happens on multiple paints, so I don't think that's the culprit. I use mostly Schmincke and Sennelier paints, both of which are recommended by various bichromate printers.
- Casein: I'm using the ammonium caseinate available through Photographer's Formulary. I'm going to use the cottage cheese method this week and see if that gives the same results. I have found that image quality goes way downhill if the casein gets old, but I get the staining problems even if it's fresh batch. I also tried lengthening the time I run it in the blender to make sure it's fully mixed. Still got the same results.
- Dichromate: I'm using a 10% potassium dichromate solution. I've tried mixing new batches (although I'm not aware that it ages) and it didn't seem to help the splotches.
- Sizing: This seems like a good suspect, but it's odd that the stains happen in different spots in each color layer. If it were a sizing problem, I would expect each paint layer to affect the same spot. I'm currently sizing with gelatin, then doing a separate formalin hardening bath. I'm experimenting this week with two layers of gelatin sizing just to see if the results change. I've used glyoxal and formalin with similar results.
- Painting technique: It's occurred to me that maybe the paint soaks into the paper if I coat it too thick. I'm using a bristle brush to apply the paint mixture, then using a foam brush to "squeegee" the mixture into a thin layer. I've gotten the best results with a thin layer of the paint mixture. The 40x50 prints are challenging to coat, but even 8x10 prints exhibit the same problems.
If you think of anything I might be missing (or if you've experienced similar problems), I would be thrilled to hear about. Thanks again for your time!